An aerosol is a suspension of fine solid particles or liquid droplets in air or another gas. Aerosols can be generated from natural or human causes. The term aerosol commonly refers to the mixture of particulates in air, and not to the particulate matter alone. Examples of natural aerosols are fog, mist or dust. Examples of human caused aerosols include particulate air pollutants, mist from the discharge at hydroelectric dams, irrigation mist, perfume from atomizers, smoke, dust, sprayed pesticides, and medical treatments for respiratory illnesses.
Several types of atmospheric aerosol have a significant effect on Earth's climate: volcanic, desert dust, sea-salt, that originating from biogenic sources and human-made. Volcanic aerosol forms in the stratosphere after an eruption as droplets of sulfuric acid that can prevail for up to two years, and reflect sunlight, lowering temperature. Desert dust, mineral particles blown to high altitudes, absorb heat and may be responsible for inhibiting storm cloud formation. Human-made sulfate aerosols, primarily from burning oil and coal, affect the behavior of clouds. When aerosols absorb pollutants, it facilitates the deposition of pollutants to the surface of the earth as well as to bodies of water. This has the potential to be damaging to both the environment and human health.
Ship tracks are clouds that form around the exhaust released by ships into the still ocean air. Water molecules collect around the tiny particles (aerosols) from exhaust to form a cloud seed. More and more water accumulates on the seed until a visible cloud is formed. In the case of ship tracks, the cloud seeds are stretched over a long narrow path where the wind has blown the ship's exhaust, so the resulting clouds resemble long strings over the ocean.
The warming caused by human-produced greenhouse gases has been somewhat offset by the cooling effect of human-produced aerosols. In 2020, regulations on fuel significantly cut sulfur dioxide emissions from international shipping by approximately 80%, leading to an unexpected global geoengineering termination shock.
The liquid or solid particles in an aerosol have diameters typically less than 1 μm. Larger particles with a significant settling speed make the mixture a suspension, but the distinction is not clear. In everyday language, aerosol often refers to a dispensing system that delivers a consumer product from a spray can.
Diseases can spread by means of small droplets in the breath, sometimes called bioaerosols.
Definitions
Aerosol is defined as a suspension system of solid or liquid particles in a gas. An aerosol includes both the particles and the suspending gas, which is usually air. Meteorologists and climatologists often refer to them as particle matter, while the classification in sizes ranges like PM2.5 or PM10, is useful in the field of atmospheric pollution as these size range play a role in ascertain the harmful effects in human health.Frederick G. Donnan presumably first used the term aerosol during World War I to describe an aero-solution, clouds of microscopic particles in air. This term developed analogously to the term hydrosol, a colloid system with water as the dispersed medium.Primary aerosols contain particles introduced directly into the gas; secondary aerosols form through gas-to-particle conversion.
Key aerosol groups include sulfates, organic carbon, black carbon, nitrates, mineral dust, and sea salt, they usually clump together to form a complex mixture. Various types of aerosol, classified according to physical form and how they were generated, include dust, fume, mist, smoke and fog.
There are several measures of aerosol concentration. Environmental science and environmental health often use the mass concentration (M), defined as the mass of particulate matter per unit volume, in units such as μg/m3. Also commonly used is the number concentration (N), the number of particles per unit volume, in units such as number per m3 or number per cm3.
Particle size has a major influence on particle properties, and the aerosol particle radius or diameter (dp) is a key property used to characterise aerosols.
Aerosols vary in their dispersity. A monodisperse aerosol, producible in the laboratory, contains particles of uniform size. Most aerosols, however, as polydisperse colloidal systems, exhibit a range of particle sizes. Liquid droplets are almost always nearly spherical, but scientists use an equivalent diameter to characterize the properties of various shapes of solid particles, some very irregular. The equivalent diameter is the diameter of a spherical particle with the same value of some physical property as the irregular particle. The equivalent volume diameter (de) is defined as the diameter of a sphere of the same volume as that of the irregular particle. Also commonly used is the aerodynamic diameter, da.
Generation and applications
People generate aerosols for various purposes, including:
- as test aerosols for calibrating instruments, performing research, and testing sampling equipment and air filters;
- to deliver deodorants, paints, and other consumer products in sprays;
- for dispersal and agricultural application
- for medical treatment of respiratory disease; and
- in fuel injection systems and other combustion technology.
Some devices for generating aerosols are:
- Aerosol spray
- Atomizer nozzle or nebulizer
- Electrospray
- Electronic cigarette
- Vibrating orifice aerosol generator (VOAG)
In the atmosphere
Several types of atmospheric aerosol have a significant effect on Earth's climate: volcanic, desert dust, sea-salt, that originating from biogenic sources and human-made. Volcanic aerosol forms in the stratosphere after an eruption as droplets of sulfuric acid that can prevail for up to two years, and reflect sunlight, lowering temperature. Desert dust, mineral particles blown to high altitudes, absorb heat and may be responsible for inhibiting storm cloud formation. Human-made sulfate aerosols, primarily from burning oil and coal, affect the behavior of clouds.
Although all hydrometeors, solid and liquid, can be described as aerosols, a distinction is commonly made between such dispersions (i.e. clouds) containing activated drops and crystals, and aerosol particles. The atmosphere of Earth contains aerosols of various types and concentrations, including quantities of:
- natural inorganic materials: fine dust, sea salt, or water droplets
- natural organic materials: smoke, pollen, spores, or bacteria
- anthropogenic products of combustion such as: smoke, ashes or dusts
Aerosols can be found in urban ecosystems in various forms, for example:
- Dust
- Cigarette smoke
- Mist from aerosol spray cans
- Soot or fumes in car exhaust
The presence of aerosols in the Earth's atmosphere can influence its climate, as well as human health.
Effects
Volcanic eruptions release large amounts of sulphuric acid, hydrogen sulfide and hydrochloric acid into the atmosphere. These gases represent aerosols and eventually return to earth as acid rain, having a number of adverse effects on the environment and human life.
When aerosols absorb pollutants, it facilitates the deposition of pollutants to the surface of the earth as well as to bodies of water. This has the potential to be damaging to both the environment and human health.
Aerosols interact with the Earth's energy budget in two ways, directly and indirectly.
- E.g., a direct effect is that aerosols scatter and absorb incoming solar radiation. This will mainly lead to a cooling of the surface (solar radiation is scattered back to space) but may also contribute to a warming of the surface (caused by the absorption of incoming solar energy). This will be an additional element to the greenhouse effect and therefore contributing to the global climate change.
- The indirect effects refer to the aerosol interfering with formations that interact directly with radiation. For example, they are able to modify the size of the cloud particles in the lower atmosphere, thereby changing the way clouds reflect and absorb light and therefore modifying the Earth's energy budget.
- There is evidence to suggest that anthropogenic aerosols actually offset the effects of greenhouse gases in some areas, which is why the Northern Hemisphere shows slower surface warming than the Southern Hemisphere, although that just means that the Northern Hemisphere will absorb the heat later through ocean currents bringing warmer waters from the South. On a global scale however, aerosol cooling decreases greenhouse-gases-induced heating without offsetting it completely.
Ship tracks are clouds that form around the exhaust released by ships into the still ocean air. Water molecules collect around the tiny particles (aerosols) from exhaust to form a cloud seed. More and more water accumulates on the seed until a visible cloud is formed. In the case of ship tracks, the cloud seeds are stretched over a long narrow path where the wind has blown the ship's exhaust, so the resulting clouds resemble long strings over the ocean.
The warming caused by human-produced greenhouse gases has been somewhat offset by the cooling effect of human-produced aerosols. In 2020, regulations on fuel significantly cut sulfur dioxide emissions from international shipping by approximately 80%, leading to an unexpected global geoengineering termination shock.
Aerosols in the 20 μm range show a particularly long persistence time in air conditioned rooms due to their "jet rider" behaviour (move with air jets, gravitationally fall out in slowly moving air); as this aerosol size is most effectively adsorbed in the human nose, the primordial infection site in COVID-19, such aerosols may contribute to the pandemic.
Aerosol particles with an effective diameter smaller than 10 μm can enter the bronchi, while the ones with an effective diameter smaller than 2.5 μm can enter as far as the gas exchange region in the lungs, which can be hazardous to human health.
Size distribution
For a monodisperse aerosol, a single number—the particle diameter—suffices to describe the size of the particles. However, more complicated particle-size distributions describe the sizes of the particles in a polydisperse aerosol. This distribution defines the relative amounts of particles, sorted according to size. One approach to defining the particle size distribution uses a list of the sizes of every particle in a sample. However, this approach proves tedious to ascertain in aerosols with millions of particles and awkward to use. Another approach splits the size range into intervals and finds the number (or proportion) of particles in each interval. These data can be presented in a histogram with the area of each bar representing the proportion of particles in that size bin, usually normalised by dividing the number of particles in a bin by the width of the interval so that the area of each bar is proportionate to the number of particles in the size range that it represents. If the width of the bins tends to zero, the frequency function is:
where
- is the diameter of the particles
- is the fraction of particles having diameters between and +
- is the frequency function
Therefore, the area under the frequency curve between two sizes a and b represents the total fraction of the particles in that size range:
It can also be formulated in terms of the total number density N:
Assuming spherical aerosol particles, the aerosol surface area per unit volume (S) is given by the second moment:
And the third moment gives the total volume concentration (V) of the particles:
The particle size distribution can be approximated. The normal distribution usually does not suitably describe particle size distributions in aerosols because of the skewness associated with a long tail of larger particles. Also for a quantity that varies over a large range, as many aerosol sizes do, the width of the distribution implies negative particles sizes, which is not physically realistic. However, the normal distribution can be suitable for some aerosols, such as test aerosols, certain pollen grains and spores.
A more widely chosen log-normal distribution gives the number frequency as:
where:
- is the standard deviation of the size distribution and
- is the arithmetic mean diameter.
The log-normal distribution has no negative values, can cover a wide range of values, and fits many observed size distributions reasonably well.
Other distributions sometimes used to characterise particle size include: the Rosin-Rammler distribution, applied to coarsely dispersed dusts and sprays; the Nukiyama–Tanasawa distribution, for sprays of extremely broad size ranges; the power function distribution, occasionally applied to atmospheric aerosols; the exponential distribution, applied to powdered materials; and for cloud droplets, the Khrgian–Mazin distribution.
Physics
Terminal velocity of a particle in a fluid
For low values of the Reynolds number (<1), true for most aerosol motion, Stokes' law describes the force of resistance on a solid spherical particle in a fluid. However, Stokes' law is only valid when the velocity of the gas at the surface of the particle is zero. For small particles (< 1 μm) that characterize aerosols, however, this assumption fails. To account for this failure, one can introduce the Cunningham correction factor, always greater than 1. Including this factor, one finds the relation between the resisting force on a particle and its velocity:
where
- is the resisting force on a spherical particle
- is the dynamic viscosity of the gas
- is the particle velocity
- is the Cunningham correction factor.
This allows us to calculate the terminal velocity of a particle undergoing gravitational settling in still air. Neglecting buoyancy effects, we find:
where
- is the terminal settling velocity of the particle.
The terminal velocity can also be derived for other kinds of forces. If Stokes' law holds, then the resistance to motion is directly proportional to speed. The constant of proportionality is the mechanical mobility (B) of a particle:
A particle traveling at any reasonable initial velocity approaches its terminal velocity exponentially with an e-folding time equal to the relaxation time:
where:
- is the particle speed at time t
- is the final particle speed
- is the initial particle speed
To account for the effect of the shape of non-spherical particles, a correction factor known as the dynamic shape factor is applied to Stokes' law. It is defined as the ratio of the resistive force of the irregular particle to that of a spherical particle with the same volume and velocity:
where:
- is the dynamic shape factor
Aerodynamic diameter
The aerodynamic diameter of an irregular particle is defined as the diameter of the spherical particle with a density of 1000 kg/m3 and the same settling velocity as the irregular particle.
Neglecting the slip correction, the particle settles at the terminal velocity proportional to the square of the aerodynamic diameter, da:
where
- = standard particle density (1000 kg/m3).
This equation gives the aerodynamic diameter:
One can apply the aerodynamic diameter to particulate pollutants or to inhaled drugs to predict where in the respiratory tract such particles deposit. Pharmaceutical companies typically use aerodynamic diameter, not geometric diameter, to characterize particles in inhalable drugs. [citation needed]
Dynamics
The previous discussion focused on single aerosol particles. In contrast, aerosol dynamics explains the evolution of complete aerosol populations. The concentrations of particles will change over time as a result of many processes. External processes that move particles outside a volume of gas under study include diffusion, gravitational settling, and electric charges and other external forces that cause particle migration. A second set of processes internal to a given volume of gas include particle formation (nucleation), evaporation, chemical reaction, and coagulation.
A differential equation called the Aerosol General Dynamic Equation (GDE) characterizes the evolution of the number density of particles in an aerosol due to these processes.
Change in time = Convective transport + brownian diffusion + gas-particle interactions + coagulation + migration by external forces
Where:
- is number density of particles of size category
- is the particle velocity
- is the particle Stokes-Einstein diffusivity
- is the particle velocity associated with an external force
Coagulation
As particles and droplets in an aerosol collide with one another, they may undergo coalescence or aggregation. This process leads to a change in the aerosol particle-size distribution, with the mode increasing in diameter as total number of particles decreases. On occasion, particles may shatter apart into numerous smaller particles; however, this process usually occurs primarily in particles too large for consideration as aerosols.
Dynamics regimes
The Knudsen number of the particle define three different dynamical regimes that govern the behaviour of an aerosol:
where is the mean free path of the suspending gas and is the diameter of the particle. For particles in the free molecular regime, Kn >> 1; particles small compared to the mean free path of the suspending gas. In this regime, particles interact with the suspending gas through a series of "ballistic" collisions with gas molecules. As such, they behave similarly to gas molecules, tending to follow streamlines and diffusing rapidly through Brownian motion. The mass flux equation in the free molecular regime is:
where a is the particle radius, P∞ and PA are the pressures far from the droplet and at the surface of the droplet respectively, kb is the Boltzmann constant, T is the temperature, CA is mean thermal velocity and α is mass accommodation coefficient.[citation needed] The derivation of this equation assumes constant pressure and constant diffusion coefficient.
Particles are in the continuum regime when Kn << 1. In this regime, the particles are big compared to the mean free path of the suspending gas, meaning that the suspending gas acts as a continuous fluid flowing round the particle. The molecular flux in this regime is:
where a is the radius of the particle A, MA is the molecular mass of the particle A, DAB is the diffusion coefficient between particles A and B, R is the ideal gas constant, T is the temperature (in absolute units like kelvin), and PA∞ and PAS are the pressures at infinite and at the surface respectively.[citation needed]
The transition regime contains all the particles in between the free molecular and continuum regimes or Kn ≈ 1. The forces experienced by a particle are a complex combination of interactions with individual gas molecules and macroscopic interactions. The semi-empirical equation describing mass flux is:
where Icont is the mass flux in the continuum regime.[citation needed] This formula is called the Fuchs-Sutugin interpolation formula. These equations do not take into account the heat release effect.
Partitioning
Aerosol partitioning theory governs condensation on and evaporation from an aerosol surface, respectively. Condensation of mass causes the mode of the particle-size distributions of the aerosol to increase; conversely, evaporation causes the mode to decrease. Nucleation is the process of forming aerosol mass from the condensation of a gaseous precursor, specifically a vapor. Net condensation of the vapor requires supersaturation, a partial pressure greater than its vapor pressure. This can happen for three reasons:[citation needed]
- Lowering the temperature of the system lowers the vapor pressure.
- Chemical reactions may increase the partial pressure of a gas or lower its vapor pressure.
- The addition of additional vapor to the system may lower the equilibrium vapor pressure according to Raoult's law.
There are two types of nucleation processes. Gases preferentially condense onto surfaces of pre-existing aerosol particles, known as heterogeneous nucleation. This process causes the diameter at the mode of particle-size distribution to increase with constant number concentration. With sufficiently high supersaturation and no suitable surfaces, particles may condense in the absence of a pre-existing surface, known as homogeneous nucleation. This results in the addition of very small, rapidly growing particles to the particle-size distribution.
Activation
Water coats particles in aerosols, making them activated, usually in the context of forming a cloud droplet (such as natural cloud seeding by aerosols from trees in a forest). Following the Kelvin equation (based on the curvature of liquid droplets), smaller particles need a higher ambient relative humidity to maintain equilibrium than larger particles do. The following formula gives relative humidity at equilibrium:
where is the saturation vapor pressure above a particle at equilibrium (around a curved liquid droplet), p0 is the saturation vapor pressure (flat surface of the same liquid) and S is the saturation ratio.
Kelvin equation for saturation vapor pressure above a curved surface is:
where rp droplet radius, σ surface tension of droplet, ρ density of liquid, M molar mass, T temperature, and R molar gas constant.
Solution to the general dynamic equation
There are no general solutions to the general dynamic equation (GDE); common methods used to solve the general dynamic equation include:
- Moment method
- Modal/sectional method, and
- Quadrature method of moments/Taylor-series expansion method of moments, and
- Monte Carlo method.
Detection
Aerosols can either be measured in-situ or with remote sensing techniques either ground-based on airborne-based.
In situ observations
Some available in situ measurement techniques include:
- Aerosol mass spectrometer (AMS)
- Differential mobility analyzer (DMA)
- Electrical aerosol spectrometer (EAS)
- (APS)
- Aerodynamic aerosol classifier (AAC)
- (WPS)
- (MOUDI)
- Condensation particle counter (CPC)
- (ELPI)
- Aerosol particle mass-analyser (APM)
- Centrifugal Particle Mass Analyser (CPMA)
Remote sensing approach
Remote sensing approaches include:
- Sun photometer
- Lidar
- Imaging spectroscopy
Size selective sampling
Particles can deposit in the nose, mouth, pharynx and larynx (the head airways region), deeper within the respiratory tract (from the trachea to the terminal bronchioles), or in the alveolar region. The location of deposition of aerosol particles within the respiratory system strongly determines the health effects of exposure to such aerosols. This phenomenon led people to invent aerosol samplers that select a subset of the aerosol particles that reach certain parts of the respiratory system.
Examples of these subsets of the particle-size distribution of an aerosol, important in occupational health, include the inhalable, thoracic, and respirable fractions. The fraction that can enter each part of the respiratory system depends on the deposition of particles in the upper parts of the airway. The inhalable fraction of particles, defined as the proportion of particles originally in the air that can enter the nose or mouth, depends on external wind speed and direction and on the particle-size distribution by aerodynamic diameter. The thoracic fraction is the proportion of the particles in ambient aerosol that can reach the thorax or chest region. The respirable fraction is the proportion of particles in the air that can reach the alveolar region. To measure the respirable fraction of particles in air, a pre-collector is used with a sampling filter. The pre-collector excludes particles as the airways remove particles from inhaled air. The sampling filter collects the particles for measurement. It is common to use cyclonic separation for the pre-collector, but other techniques include impactors, horizontal elutriators, and large pore membrane filters.
Two alternative size-selective criteria, often used in atmospheric monitoring, are PM10 and PM2.5. PM10 is defined by ISO as particles which pass through a size-selective inlet with a 50% efficiency cut-off at 10 μm aerodynamic diameter and PM2.5 as particles which pass through a size-selective inlet with a 50% efficiency cut-off at 2.5 μm aerodynamic diameter. PM10 corresponds to the "thoracic convention" as defined in ISO 7708:1995, Clause 6; PM2.5 corresponds to the "high-risk respirable convention" as defined in ISO 7708:1995, 7.1. The United States Environmental Protection Agency replaced the older standards for particulate matter based on Total Suspended Particulate with another standard based on PM10 in 1987 and then introduced standards for PM2.5 (also known as fine particulate matter) in 1997.
See also
- Aerogel
- Aeroplankton
- Aerosol transmission
- Bioaerosol
- Deposition (Aerosol physics)
- Global dimming
- Nebulizer
- Monoterpene
- Stratospheric aerosol injection
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External links
- International Aerosol Research Assembly Archived 2020-01-21 at the Wayback Machine
- American Association for Aerosol Research
- NIOSH Manual of Analytical Methods (see chapters on aerosol sampling)
An aerosol is a suspension of fine solid particles or liquid droplets in air or another gas Aerosols can be generated from natural or human causes The term aerosol commonly refers to the mixture of particulates in air and not to the particulate matter alone Examples of natural aerosols are fog mist or dust Examples of human caused aerosols include particulate air pollutants mist from the discharge at hydroelectric dams irrigation mist perfume from atomizers smoke dust sprayed pesticides and medical treatments for respiratory illnesses Mist and fog are aerosols Several types of atmospheric aerosol have a significant effect on Earth s climate volcanic desert dust sea salt that originating from biogenic sources and human made Volcanic aerosol forms in the stratosphere after an eruption as droplets of sulfuric acid that can prevail for up to two years and reflect sunlight lowering temperature Desert dust mineral particles blown to high altitudes absorb heat and may be responsible for inhibiting storm cloud formation Human made sulfate aerosols primarily from burning oil and coal affect the behavior of clouds When aerosols absorb pollutants it facilitates the deposition of pollutants to the surface of the earth as well as to bodies of water This has the potential to be damaging to both the environment and human health Ship tracks are clouds that form around the exhaust released by ships into the still ocean air Water molecules collect around the tiny particles aerosols from exhaust to form a cloud seed More and more water accumulates on the seed until a visible cloud is formed In the case of ship tracks the cloud seeds are stretched over a long narrow path where the wind has blown the ship s exhaust so the resulting clouds resemble long strings over the ocean The warming caused by human produced greenhouse gases has been somewhat offset by the cooling effect of human produced aerosols In 2020 regulations on fuel significantly cut sulfur dioxide emissions from international shipping by approximately 80 leading to an unexpected global geoengineering termination shock The liquid or solid particles in an aerosol have diameters typically less than 1 mm Larger particles with a significant settling speed make the mixture a suspension but the distinction is not clear In everyday language aerosol often refers to a dispensing system that delivers a consumer product from a spray can Diseases can spread by means of small droplets in the breath sometimes called bioaerosols DefinitionsPhotomicrograph made with a Scanning Electron Microscope SEM Fly ash particles at 2 000 magnification Most of the particles in this aerosol are nearly spherical Aerosol spray can Aerosol is defined as a suspension system of solid or liquid particles in a gas An aerosol includes both the particles and the suspending gas which is usually air Meteorologists and climatologists often refer to them as particle matter while the classification in sizes ranges like PM2 5 or PM10 is useful in the field of atmospheric pollution as these size range play a role in ascertain the harmful effects in human health Frederick G Donnan presumably first used the term aerosol during World War I to describe an aero solution clouds of microscopic particles in air This term developed analogously to the term hydrosol a colloid system with water as the dispersed medium Primary aerosols contain particles introduced directly into the gas secondary aerosols form through gas to particle conversion Key aerosol groups include sulfates organic carbon black carbon nitrates mineral dust and sea salt they usually clump together to form a complex mixture Various types of aerosol classified according to physical form and how they were generated include dust fume mist smoke and fog There are several measures of aerosol concentration Environmental science and environmental health often use the mass concentration M defined as the mass of particulate matter per unit volume in units such as mg m3 Also commonly used is the number concentration N the number of particles per unit volume in units such as number per m3 or number per cm3 Particle size has a major influence on particle properties and the aerosol particle radius or diameter dp is a key property used to characterise aerosols Aerosols vary in their dispersity A monodisperse aerosol producible in the laboratory contains particles of uniform size Most aerosols however as polydisperse colloidal systems exhibit a range of particle sizes Liquid droplets are almost always nearly spherical but scientists use an equivalent diameter to characterize the properties of various shapes of solid particles some very irregular The equivalent diameter is the diameter of a spherical particle with the same value of some physical property as the irregular particle The equivalent volume diameter de is defined as the diameter of a sphere of the same volume as that of the irregular particle Also commonly used is the aerodynamic diameter da Generation and applicationsPeople generate aerosols for various purposes including as test aerosols for calibrating instruments performing research and testing sampling equipment and air filters to deliver deodorants paints and other consumer products in sprays for dispersal and agricultural application for medical treatment of respiratory disease and in fuel injection systems and other combustion technology Some devices for generating aerosols are Aerosol spray Atomizer nozzle or nebulizer Electrospray Electronic cigarette Vibrating orifice aerosol generator VOAG In the atmosphereAerosol pollution over northern India and BangladeshOverview of large clouds of aerosols around Earth green smoke blue salt yellow dust white sulfuric Several types of atmospheric aerosol have a significant effect on Earth s climate volcanic desert dust sea salt that originating from biogenic sources and human made Volcanic aerosol forms in the stratosphere after an eruption as droplets of sulfuric acid that can prevail for up to two years and reflect sunlight lowering temperature Desert dust mineral particles blown to high altitudes absorb heat and may be responsible for inhibiting storm cloud formation Human made sulfate aerosols primarily from burning oil and coal affect the behavior of clouds Although all hydrometeors solid and liquid can be described as aerosols a distinction is commonly made between such dispersions i e clouds containing activated drops and crystals and aerosol particles The atmosphere of Earth contains aerosols of various types and concentrations including quantities of natural inorganic materials fine dust sea salt or water droplets natural organic materials smoke pollen spores or bacteria anthropogenic products of combustion such as smoke ashes or dusts Aerosols can be found in urban ecosystems in various forms for example Dust Cigarette smoke Mist from aerosol spray cans Soot or fumes in car exhaust The presence of aerosols in the Earth s atmosphere can influence its climate as well as human health Effects Aerosols have a cooling effect that is small compared to the radiative forcing warming effect of greenhouse gases Volcanic eruptions release large amounts of sulphuric acid hydrogen sulfide and hydrochloric acid into the atmosphere These gases represent aerosols and eventually return to earth as acid rain having a number of adverse effects on the environment and human life When aerosols absorb pollutants it facilitates the deposition of pollutants to the surface of the earth as well as to bodies of water This has the potential to be damaging to both the environment and human health Aerosols interact with the Earth s energy budget in two ways directly and indirectly E g a direct effect is that aerosols scatter and absorb incoming solar radiation This will mainly lead to a cooling of the surface solar radiation is scattered back to space but may also contribute to a warming of the surface caused by the absorption of incoming solar energy This will be an additional element to the greenhouse effect and therefore contributing to the global climate change The indirect effects refer to the aerosol interfering with formations that interact directly with radiation For example they are able to modify the size of the cloud particles in the lower atmosphere thereby changing the way clouds reflect and absorb light and therefore modifying the Earth s energy budget There is evidence to suggest that anthropogenic aerosols actually offset the effects of greenhouse gases in some areas which is why the Northern Hemisphere shows slower surface warming than the Southern Hemisphere although that just means that the Northern Hemisphere will absorb the heat later through ocean currents bringing warmer waters from the South On a global scale however aerosol cooling decreases greenhouse gases induced heating without offsetting it completely Ship tracks are clouds that form around the exhaust released by ships into the still ocean air Water molecules collect around the tiny particles aerosols from exhaust to form a cloud seed More and more water accumulates on the seed until a visible cloud is formed In the case of ship tracks the cloud seeds are stretched over a long narrow path where the wind has blown the ship s exhaust so the resulting clouds resemble long strings over the ocean The warming caused by human produced greenhouse gases has been somewhat offset by the cooling effect of human produced aerosols In 2020 regulations on fuel significantly cut sulfur dioxide emissions from international shipping by approximately 80 leading to an unexpected global geoengineering termination shock Aerosols in the 20 mm range show a particularly long persistence time in air conditioned rooms due to their jet rider behaviour move with air jets gravitationally fall out in slowly moving air as this aerosol size is most effectively adsorbed in the human nose the primordial infection site in COVID 19 such aerosols may contribute to the pandemic Aerosol particles with an effective diameter smaller than 10 mm can enter the bronchi while the ones with an effective diameter smaller than 2 5 mm can enter as far as the gas exchange region in the lungs which can be hazardous to human health Size distributionThe same hypothetical log normal bi modal aerosol distribution plotted from top to bottom as a number vs diameter distribution a surface area vs diameter distribution and a volume vs diameter distribution Typical mode names are shown at the top Each distribution is normalized so that the total area is 1000 For a monodisperse aerosol a single number the particle diameter suffices to describe the size of the particles However more complicated particle size distributions describe the sizes of the particles in a polydisperse aerosol This distribution defines the relative amounts of particles sorted according to size One approach to defining the particle size distribution uses a list of the sizes of every particle in a sample However this approach proves tedious to ascertain in aerosols with millions of particles and awkward to use Another approach splits the size range into intervals and finds the number or proportion of particles in each interval These data can be presented in a histogram with the area of each bar representing the proportion of particles in that size bin usually normalised by dividing the number of particles in a bin by the width of the interval so that the area of each bar is proportionate to the number of particles in the size range that it represents If the width of the bins tends to zero the frequency function is df f dp ddp displaystyle mathrm d f f d p mathrm d d p where dp displaystyle d p is the diameter of the particles df displaystyle mathrm d f is the fraction of particles having diameters between dp displaystyle d p and dp displaystyle d p ddp displaystyle mathrm d d p f dp displaystyle f d p is the frequency function Therefore the area under the frequency curve between two sizes a and b represents the total fraction of the particles in that size range fab abf dp ddp displaystyle f ab int a b f d p mathrm d d p It can also be formulated in terms of the total number density N dN N dp ddp displaystyle dN N d p mathrm d d p Assuming spherical aerosol particles the aerosol surface area per unit volume S is given by the second moment S p 2 0 N dp dp2ddp displaystyle S pi 2 int 0 infty N d p d p 2 mathrm d d p And the third moment gives the total volume concentration V of the particles V p 6 0 N dp dp3ddp displaystyle V pi 6 int 0 infty N d p d p 3 mathrm d d p The particle size distribution can be approximated The normal distribution usually does not suitably describe particle size distributions in aerosols because of the skewness associated with a long tail of larger particles Also for a quantity that varies over a large range as many aerosol sizes do the width of the distribution implies negative particles sizes which is not physically realistic However the normal distribution can be suitable for some aerosols such as test aerosols certain pollen grains and spores A more widely chosen log normal distribution gives the number frequency as df 1dps2pe ln dp dp 22s2ddp displaystyle mathrm d f frac 1 d p sigma sqrt 2 pi e frac ln d p bar d p 2 2 sigma 2 mathrm d d p where s displaystyle sigma is the standard deviation of the size distribution and dp displaystyle bar d p is the arithmetic mean diameter The log normal distribution has no negative values can cover a wide range of values and fits many observed size distributions reasonably well Other distributions sometimes used to characterise particle size include the Rosin Rammler distribution applied to coarsely dispersed dusts and sprays the Nukiyama Tanasawa distribution for sprays of extremely broad size ranges the power function distribution occasionally applied to atmospheric aerosols the exponential distribution applied to powdered materials and for cloud droplets the Khrgian Mazin distribution PhysicsTerminal velocity of a particle in a fluid For low values of the Reynolds number lt 1 true for most aerosol motion Stokes law describes the force of resistance on a solid spherical particle in a fluid However Stokes law is only valid when the velocity of the gas at the surface of the particle is zero For small particles lt 1 mm that characterize aerosols however this assumption fails To account for this failure one can introduce the Cunningham correction factor always greater than 1 Including this factor one finds the relation between the resisting force on a particle and its velocity FD 3phVdCc displaystyle F D frac 3 pi eta Vd C c where FD displaystyle F D is the resisting force on a spherical particle h displaystyle eta is the dynamic viscosity of the gas V displaystyle V is the particle velocity Cc displaystyle C c is the Cunningham correction factor This allows us to calculate the terminal velocity of a particle undergoing gravitational settling in still air Neglecting buoyancy effects we find VTS rpd2gCc18h displaystyle V TS frac rho p d 2 gC c 18 eta where VTS displaystyle V TS is the terminal settling velocity of the particle The terminal velocity can also be derived for other kinds of forces If Stokes law holds then the resistance to motion is directly proportional to speed The constant of proportionality is the mechanical mobility B of a particle B VFD Cc3phd displaystyle B frac V F D frac C c 3 pi eta d A particle traveling at any reasonable initial velocity approaches its terminal velocity exponentially with an e folding time equal to the relaxation time V t Vf Vf V0 e tt displaystyle V t V f V f V 0 e frac t tau where V t displaystyle V t is the particle speed at time t Vf displaystyle V f is the final particle speed V0 displaystyle V 0 is the initial particle speed To account for the effect of the shape of non spherical particles a correction factor known as the dynamic shape factor is applied to Stokes law It is defined as the ratio of the resistive force of the irregular particle to that of a spherical particle with the same volume and velocity x FD3phVde displaystyle chi frac F D 3 pi eta Vd e where x displaystyle chi is the dynamic shape factorAerodynamic diameter The aerodynamic diameter of an irregular particle is defined as the diameter of the spherical particle with a density of 1000 kg m3 and the same settling velocity as the irregular particle Neglecting the slip correction the particle settles at the terminal velocity proportional to the square of the aerodynamic diameter da VTS r0da2g18h displaystyle V TS frac rho 0 d a 2 g 18 eta where r0 displaystyle rho 0 standard particle density 1000 kg m3 This equation gives the aerodynamic diameter da de rpr0x 12 displaystyle d a d e left frac rho p rho 0 chi right frac 1 2 One can apply the aerodynamic diameter to particulate pollutants or to inhaled drugs to predict where in the respiratory tract such particles deposit Pharmaceutical companies typically use aerodynamic diameter not geometric diameter to characterize particles in inhalable drugs citation needed Dynamics The previous discussion focused on single aerosol particles In contrast aerosol dynamics explains the evolution of complete aerosol populations The concentrations of particles will change over time as a result of many processes External processes that move particles outside a volume of gas under study include diffusion gravitational settling and electric charges and other external forces that cause particle migration A second set of processes internal to a given volume of gas include particle formation nucleation evaporation chemical reaction and coagulation A differential equation called the Aerosol General Dynamic Equation GDE characterizes the evolution of the number density of particles in an aerosol due to these processes ni t niq Dp ini ni t growth ni t coag qFni displaystyle frac partial n i partial t nabla cdot n i mathbf q nabla cdot D p nabla i n i left frac partial n i partial t right mathrm growth left frac partial n i partial t right mathrm coag nabla cdot mathbf q F n i Change in time Convective transport brownian diffusion gas particle interactions coagulation migration by external forces Where ni displaystyle n i is number density of particles of size category i displaystyle i q displaystyle mathbf q is the particle velocity Dp displaystyle D p is the particle Stokes Einstein diffusivity qF displaystyle mathbf q F is the particle velocity associated with an external forceCoagulation As particles and droplets in an aerosol collide with one another they may undergo coalescence or aggregation This process leads to a change in the aerosol particle size distribution with the mode increasing in diameter as total number of particles decreases On occasion particles may shatter apart into numerous smaller particles however this process usually occurs primarily in particles too large for consideration as aerosols Dynamics regimes The Knudsen number of the particle define three different dynamical regimes that govern the behaviour of an aerosol Kn 2ld displaystyle K n frac 2 lambda d where l displaystyle lambda is the mean free path of the suspending gas and d displaystyle d is the diameter of the particle For particles in the free molecular regime Kn gt gt 1 particles small compared to the mean free path of the suspending gas In this regime particles interact with the suspending gas through a series of ballistic collisions with gas molecules As such they behave similarly to gas molecules tending to follow streamlines and diffusing rapidly through Brownian motion The mass flux equation in the free molecular regime is I pa2kb P T PATA CAa displaystyle I frac pi a 2 k b left frac P infty T infty frac P A T A right cdot C A alpha where a is the particle radius P and PA are the pressures far from the droplet and at the surface of the droplet respectively kb is the Boltzmann constant T is the temperature CA is mean thermal velocity and a is mass accommodation coefficient citation needed The derivation of this equation assumes constant pressure and constant diffusion coefficient Particles are in the continuum regime when Kn lt lt 1 In this regime the particles are big compared to the mean free path of the suspending gas meaning that the suspending gas acts as a continuous fluid flowing round the particle The molecular flux in this regime is Icont 4paMADABRT PA PAS displaystyle I cont sim frac 4 pi aM A D AB RT left P A infty P AS right where a is the radius of the particle A MA is the molecular mass of the particle A DAB is the diffusion coefficient between particles A and B R is the ideal gas constant T is the temperature in absolute units like kelvin and PA and PAS are the pressures at infinite and at the surface respectively citation needed The transition regime contains all the particles in between the free molecular and continuum regimes or Kn 1 The forces experienced by a particle are a complex combination of interactions with individual gas molecules and macroscopic interactions The semi empirical equation describing mass flux is I Icont 1 Kn1 1 71Kn 1 33Kn2 displaystyle I I cont cdot frac 1 K n 1 1 71K n 1 33 K n 2 where Icont is the mass flux in the continuum regime citation needed This formula is called the Fuchs Sutugin interpolation formula These equations do not take into account the heat release effect Partitioning Condensation and evaporation Aerosol partitioning theory governs condensation on and evaporation from an aerosol surface respectively Condensation of mass causes the mode of the particle size distributions of the aerosol to increase conversely evaporation causes the mode to decrease Nucleation is the process of forming aerosol mass from the condensation of a gaseous precursor specifically a vapor Net condensation of the vapor requires supersaturation a partial pressure greater than its vapor pressure This can happen for three reasons citation needed Lowering the temperature of the system lowers the vapor pressure Chemical reactions may increase the partial pressure of a gas or lower its vapor pressure The addition of additional vapor to the system may lower the equilibrium vapor pressure according to Raoult s law There are two types of nucleation processes Gases preferentially condense onto surfaces of pre existing aerosol particles known as heterogeneous nucleation This process causes the diameter at the mode of particle size distribution to increase with constant number concentration With sufficiently high supersaturation and no suitable surfaces particles may condense in the absence of a pre existing surface known as homogeneous nucleation This results in the addition of very small rapidly growing particles to the particle size distribution Activation Water coats particles in aerosols making them activated usually in the context of forming a cloud droplet such as natural cloud seeding by aerosols from trees in a forest Following the Kelvin equation based on the curvature of liquid droplets smaller particles need a higher ambient relative humidity to maintain equilibrium than larger particles do The following formula gives relative humidity at equilibrium RH psp0 100 S 100 displaystyle RH frac p s p 0 times 100 S times 100 where ps displaystyle p s is the saturation vapor pressure above a particle at equilibrium around a curved liquid droplet p0 is the saturation vapor pressure flat surface of the same liquid and S is the saturation ratio Kelvin equation for saturation vapor pressure above a curved surface is ln psp0 2sMRTr rp displaystyle ln p s over p 0 frac 2 sigma M RT rho cdot r p where rp droplet radius s surface tension of droplet r density of liquid M molar mass T temperature and R molar gas constant Solution to the general dynamic equation There are no general solutions to the general dynamic equation GDE common methods used to solve the general dynamic equation include Moment method Modal sectional method and Quadrature method of moments Taylor series expansion method of moments and Monte Carlo method DetectionAerosols can either be measured in situ or with remote sensing techniques either ground based on airborne based In situ observations Some available in situ measurement techniques include Aerosol mass spectrometer AMS Differential mobility analyzer DMA Electrical aerosol spectrometer EAS APS Aerodynamic aerosol classifier AAC WPS MOUDI Condensation particle counter CPC ELPI Aerosol particle mass analyser APM Centrifugal Particle Mass Analyser CPMA Remote sensing approach Remote sensing approaches include Sun photometer Lidar Imaging spectroscopySize selective sampling Particles can deposit in the nose mouth pharynx and larynx the head airways region deeper within the respiratory tract from the trachea to the terminal bronchioles or in the alveolar region The location of deposition of aerosol particles within the respiratory system strongly determines the health effects of exposure to such aerosols This phenomenon led people to invent aerosol samplers that select a subset of the aerosol particles that reach certain parts of the respiratory system Examples of these subsets of the particle size distribution of an aerosol important in occupational health include the inhalable thoracic and respirable fractions The fraction that can enter each part of the respiratory system depends on the deposition of particles in the upper parts of the airway The inhalable fraction of particles defined as the proportion of particles originally in the air that can enter the nose or mouth depends on external wind speed and direction and on the particle size distribution by aerodynamic diameter The thoracic fraction is the proportion of the particles in ambient aerosol that can reach the thorax or chest region The respirable fraction is the proportion of particles in the air that can reach the alveolar region To measure the respirable fraction of particles in air a pre collector is used with a sampling filter The pre collector excludes particles as the airways remove particles from inhaled air The sampling filter collects the particles for measurement It is common to use cyclonic separation for the pre collector but other techniques include impactors horizontal elutriators and large pore membrane filters Two alternative size selective criteria often used in atmospheric monitoring are PM10 and PM2 5 PM10 is defined by ISO as particles which pass through a size selective inlet with a 50 efficiency cut off at 10 mm aerodynamic diameter and PM2 5 as particles which pass through a size selective inlet with a 50 efficiency cut off at 2 5 mm aerodynamic diameter PM10 corresponds to the thoracic convention as defined in ISO 7708 1995 Clause 6 PM2 5 corresponds to the high risk respirable convention as defined in ISO 7708 1995 7 1 The United States Environmental Protection Agency replaced the older standards for particulate matter based on Total Suspended Particulate with another standard based on PM10 in 1987 and then introduced standards for PM2 5 also known as fine particulate matter in 1997 See alsoAerogel Aeroplankton Aerosol transmission Bioaerosol Deposition Aerosol physics Global dimming Nebulizer Monoterpene Stratospheric aerosol injectionReferencesHinds 1999 p 3 Seinfeld J Pandis S 1998 Atmospheric Chemistry and Physics From Air Pollution to Climate Change 2nd ed Hoboken New Jersey John Wiley amp Sons p 97 ISBN 978 0 471 17816 3 Hidy 1984 p 254 Atmospheric Aerosols What Are They and Why Are They So Important NASA Langley Research Center 22 Apr 2008 Retrieved 27 December 2014 Kommalapati Raghava R Valsaraj Kalliat T 2009 Atmospheric aerosols Characterization chemistry modeling and climate Vol 1005 Washington DC American Chemical Society pp 1 10 doi 10 1021 bk 2009 1005 ch001 ISBN 978 0 8412 2482 7 Yuan Tianle Song Hua Oreopoulos Lazaros Wood Robert Bian Huisheng Breen Katherine Chin Mian Yu Hongbin Barahona Donifan Meyer Kerry Platnick Steven 2024 05 30 Abrupt reduction in shipping emission as an inadvertent geoengineering termination shock produces substantial radiative warming Communications Earth amp Environment 5 1 281 Bibcode 2024ComEE 5 281Y doi 10 1038 s43247 024 01442 3 ISSN 2662 4435 PMC 11139642 PMID 38826490 Hunziker Patrick 2021 10 01 Minimising exposure to respiratory droplets jet riders and aerosols in air conditioned hospital rooms by a Shield and Sink strategy BMJ Open 11 10 e047772 doi 10 1136 bmjopen 2020 047772 ISSN 2044 6055 PMC 8520596 PMID 34642190 Fuller Joanna Kotcher 2017 01 31 Surgical Technology E Book Principles and Practice Elsevier Health Sciences ISBN 978 0 323 43056 2 PM2 5 refers to the mass of particles with sizes between 0 and 2 5 micrometers and PM10 for sizes between 0 and 10 micrometers Aerosols Tiny Particles Big Impact earthobservatory nasa gov 2 November 2010 US EPA OAR 2016 04 19 Particulate Matter PM Basics www epa gov Retrieved 2024 11 04 Hidy 1984 p 5 Hinds 1999 p 8 Colbeck amp Lazaridis 2014 p Ch 1 1 Hinds 1999 pp 10 11 Hinds 1999 p 10 Hinds 1999 p 51 Hinds 1999 p 428 Hidy 1984 p 255 Hidy 1984 p 274 Hidy 1984 p 278 The water in atmospheric modelling has an important role with a particular behavior their different phases vapor liquid and solid are mostly conditioned by temperature which differentiate in practical terms the hydrometeors from other atmospheric particles Forster Piers M Smith Christopher J Walsh Tristram Lamb William F et al 2023 Indicators of Global Climate Change 2022 annual update of large scale indicators of the state of the climate system and human influence PDF Earth System Science Data 15 6 Copernicus Programme 2295 2327 Bibcode 2023ESSD 15 2295F doi 10 5194 essd 15 2295 2023 Fig 2 a Allen Bob Atmospheric Aerosols What Are They and Why Are They So Important NASA Retrieved 8 July 2014 Highwood Ellie 2018 09 05 Aerosols and Climate Royal Meteorological Society Retrieved 2019 10 07 Fifth Assessment Report Climate Change 2013 www ipcc ch Retrieved 2018 02 07 Anthropogenic Aerosols Greenhouse Gases and the Uptake Transport and Storage of Excess Heat in the Climate System Irving D B Wijffels S Church J A 2019 Anthropogenic Aerosols Greenhouse Gases and the Uptake Transport and Storage of Excess Heat in the Climate System Geophysical Research Letters 46 9 4894 4903 Bibcode 2019GeoRL 46 4894I doi 10 1029 2019GL082015 hdl 1912 24327 GIEC AR6 WG1 Figure SPM 2 https www ipcc ch report sixth assessment report working group i Wellock Bill 2024 01 17 Changing the sky FSU researchers examine how aerosols from ships affect cloud formation climate change Florida State University News Retrieved 2024 07 15 Hunziker Patrick 2020 12 16 Minimizing exposure to respiratory droplets jet riders and aerosols in air conditioned hospital rooms by a Shield and Sink strategy medRxiv 10 1101 2020 12 08 20233056v1 Kesavanathan Jana Swift David L 1998 Human Nasal Passage Particle Deposition The Effect of Particle Size Flow Rate and Anatomical Factors Aerosol Science and Technology 28 5 457 463 Bibcode 1998AerST 28 457K doi 10 1080 02786829808965537 ISSN 0278 6826 McNeill VF June 2022 Airborne Transmission of SARS CoV 2 Evidence and Implications for Engineering Controls Annual Review of Chemical and Biomolecular Engineering 13 1 123 140 doi 10 1146 annurev chembioeng 092220 111631 PMID 35300517 S2CID 247520571 Grainger Don Volcanic Emissions Earth Observation Data Group Department of Physics University of Oxford University of Oxford Retrieved 8 July 2014 Jillavenkatesa A Dapkunas SJ Lin Sien Lum 2001 Particle Size Characterization NIST Special Publication 960 1 Hinds 1999 pp 75 77 Hinds 1999 p 79 Hidy 1984 p 58 Hinds 1999 p 90 Hinds 1999 p 91 There is also a practical advantage of modelling the aerosols size distributions with a log normal distribution as thee n th moment of a log normally distributed variable X has a simple analytical expression using the two parameters s displaystyle sigma and m displaystyle mu which simplifies the model Hinds 1999 pp 104 5 Hinds 1999 p 44 49 Hinds 1999 p 49 Hinds 1999 p 47 Hinds 1999 p 115 Hinds 1999 p 53 Hinds 1999 p 54 Hidy 1984 p 60 Hinds 1999 p 260 Baron P A amp Willeke K 2001 Gas and Particle Motion Aerosol Measurement Principles Techniques and Applications DeCarlo P F 2004 Particle Morphology and Density Characterization by Combined Mobility and Aerodynamic Diameter Measurements Part 1 Theory Aerosol Science and Technology 38 12 1185 1205 Bibcode 2004AerST 38 1185D doi 10 1080 027868290903907 Hinds 1999 p 288 Spracklen Dominick V Bonn Boris Carslaw Kenneth S 2008 12 28 Boreal forests aerosols and the impacts on clouds and climate Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences 366 1885 4613 4626 Bibcode 2008RSPTA 366 4613S doi 10 1098 rsta 2008 0201 ISSN 1364 503X PMID 18826917 S2CID 206156442 Hidy 1984 p 62 Friedlander 2000 Hulburt H M Katz S 1964 Some problems in particle technology Chemical Engineering Science 19 8 555 574 doi 10 1016 0009 2509 64 85047 8 Landgrebe James D Pratsinis Sotiris E 1990 A discrete sectional model for particulate production by gas phase chemical reaction and aerosol coagulation in the free molecular regime Journal of Colloid and Interface Science 139 1 63 86 Bibcode 1990JCIS 139 63L doi 10 1016 0021 9797 90 90445 T McGraw Robert 1997 Description of Aerosol Dynamics by the Quadrature Method of Moments Aerosol Science and Technology 27 2 255 265 Bibcode 1997AerST 27 255M doi 10 1080 02786829708965471 Marchisio Daniele L Fox Rodney O 2005 Solution of population balance equations using the direct quadrature method of moments Journal of Aerosol Science 36 1 43 73 Bibcode 2005JAerS 36 43M doi 10 1016 j jaerosci 2004 07 009 Yu Mingzhou Lin Jianzhong Chan Tatleung 2008 A New Moment Method for Solving the Coagulation Equation for Particles in Brownian Motion Aerosol Science and Technology 42 9 705 713 Bibcode 2008AerST 42 705Y doi 10 1080 02786820802232972 hdl 10397 9612 S2CID 120582575 Yu Mingzhou Lin Jianzhong 2009 Taylor expansion moment method for agglomerate coagulation due to Brownian motion in the entire size regime Journal of Aerosol Science 40 6 549 562 Bibcode 2009JAerS 40 549Y doi 10 1016 j jaerosci 2009 03 001 Kraft Murkus 2005 Modelling of Particulate Processes KONA Powder and Particle Journal 23 18 35 doi 10 14356 kona 2005007 Hinds 1999 p 233 Hinds 1999 p 249 Hinds 1999 p 244 Hinds 1999 p 246 Hinds 1999 p 254 Hinds 1999 p 250 Hinds 1999 p 252 Particulate pollution PM10 and PM2 5 Recognition Evaluation Control News and views from Diamond Environmental Limited 2010 12 10 Retrieved 23 September 2012 Particulate Matter PM 10 Archived from the original on 1 September 2012 Retrieved 23 September 2012 Basic Information Retrieved 23 September 2012 Sources Colbeck Ian Lazaridis Mihalis eds 2014 Aerosol Science Technology and Applications John Wiley amp Sons Science ISBN 978 1 119 97792 6 Friedlander S K 2000 Smoke Dust and Haze Fundamentals of Aerosol Behavior 2nd ed New York Oxford University Press ISBN 0 19 512999 7 Hinds William C 1999 Aerosol Technology 2nd ed Wiley Interscience ISBN 978 0 471 19410 1 Hidy George M 1984 Aerosols An Industrial and Environmental Science Academic Press Inc ISBN 978 0 12 412336 6 External linksWikimedia Commons has media related to Aerosols International Aerosol Research Assembly Archived 2020 01 21 at the Wayback Machine American Association for Aerosol Research NIOSH Manual of Analytical Methods see chapters on aerosol sampling